Redox-activeconjugatedmicroporouspolymers(RCMPs)havereceivedremarkableinterestinelectrochemicalenergy-storagesystemsinviewoftheirporousstructureandtunableredoxnature.ThisworkpresentsaneffectivestrategytoconstructRCMPswithbipolaranddoubleredox-activecentersbyintegratingcopper(II)tetraaminephthalocyanine(CuTAPc)and1,4,5,8-naphthalenetetracarboxylicdianhydride(NTCDA)unitsintotheRCMPs(CuPcNA-CMP).Asexpected,CuPcNA-CMPhaspotentialapplicationinthehalfcellsofdual-ionbatteries(lithiumbasedDIBs,LDIBs),asymmetricDIBs(graphitebasedDIBs,ADIBs),andsymmetricDIBs(allorganicDIBs,SDIBs).Amongthem,LDIBsshowahighreversiblecapacity(202.4mAhg?1at0.2Ag?1)andexcellentratecapability(86.1mAhg?1at5Ag?1).AndADIBsalsoshowahighreversiblecapacity(245.3mAhg?1at0.1Ag?1),longcyclestabilitywithcapacityretentionof89%after500cycles,andgoodrateperformance(125.1mAhg?1at5Ag?1).Inaddition,SDIBsshowhighinitialcharge/dischargecapacitiesof269.4/198.5mAhg?1at0.05Ag?1andahighcellvoltageof2.5V.Meanwhile,themechanismofCuPcNA-CMPonhostingbothanions(PF6?)andcations(Li+)isinvestigatedbydetailedexperimentalanalysisanddensityfunctionaltheorystudies.
For search and rescue (SAR), the group unmanned aerial vehicle (GUAV) can rapidly cover the disaster area, and it can provide reliable connectivity to victim by aerial backbone network (ABN). However, existing 3D aerial mobility model (3D AMM) cannot capture unique features of GUAV in SAR, especially smooth 3D trajectory and collision avoidance. In this paper, we develop realistic 3D aerial group mobility model based on spiral line (3D SLGM) for SAR. Firstly, we review some related works. Then, we introduce the mechanism of 3D SLGM, such as Z-Or-SLGM and Z-Non-SLGM. Furthermore, we analyze some mathematical features of 3D SLGM. In addition, we investigate key mobility features of 3D SLGM. Finally, we evaluate the network performance under 3D SLGM. The result shows that 3D SLGM has smooth 3D trajectory and uniform distribution of spatial nodes in 3D space. With the collided rate of 0%, 3D SLGM merely takes about 1.4 minutes to cover 100% of the target area of 200 m*200 m. Besides, the network under 3D SLGM can approach the throughput of 0.45 Mb/s, the end-to-end delay of 3.2 ms and the loss packets rate of 0%. We believe that 3D SLGM, as a significant supplement of 3D AMM, can provide many helpful guidelines in the design and analysis of authentic ABN.
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